Homogeneous RuCl
                        2
                        (PPh
                        3
                        )
                        3
                        -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor

Sudip Mukhopadhyay; Anan Yaghmur; Axel Benichou; Yoel Sasson

Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor

Sudip Mukhopadhyay, Anan Yaghmur, Axel Benichou, Yoel Sasson

2 Citations (Scopus)

Abstract

The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.

Original language	English
Journal	Organic Process Research and Development
Volume	4
Issue number	6
Pages (from-to)	571-574
Number of pages	4
ISSN	1083-6160
Publication status	Published - 1 Nov 2000

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Mukhopadhyay, S., Yaghmur, A., Benichou, A., & Sasson, Y. (2000). Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor. Organic Process Research and Development, 4(6), 571-574.

Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor. / Mukhopadhyay, Sudip; Yaghmur, Anan; Benichou, Axel et al.

In: Organic Process Research and Development, Vol. 4, No. 6, 01.11.2000, p. 571-574.

Research output: Contribution to journal › Journal article › Research › peer-review

Mukhopadhyay, S, Yaghmur, A, Benichou, A & Sasson, Y 2000, 'Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor', Organic Process Research and Development, vol. 4, no. 6, pp. 571-574.

Mukhopadhyay S, Yaghmur A, Benichou A, Sasson Y. Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor. Organic Process Research and Development. 2000 Nov 1;4(6):571-574.

Mukhopadhyay, Sudip ; Yaghmur, Anan ; Benichou, Axel et al. / Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor. In: Organic Process Research and Development. 2000 ; Vol. 4, No. 6. pp. 571-574.

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title = "Homogeneous RuCl 2 (PPh 3 ) 3 -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor",

abstract = "The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.",

author = "Sudip Mukhopadhyay and Anan Yaghmur and Axel Benichou and Yoel Sasson",

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T1 - Homogeneous RuCl 2 (PPh 3 ) 3 -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor

AU - Mukhopadhyay, Sudip

AU - Yaghmur, Anan

AU - Benichou, Axel

AU - Sasson, Yoel

PY - 2000/11/1

Y1 - 2000/11/1

N2 - The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.

AB - The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.

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M3 - Journal article

AN - SCOPUS:0034345920

SN - 1083-6160

VL - 4

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EP - 574

JO - Organic Process Research and Development

JF - Organic Process Research and Development

IS - 6

ER -

Homogeneous RuCl ₂ (PPh ₃ ) ₃ -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor

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