Abstract
We consider a large atom with nuclear charge Z described by non-relativistic quantum mechanics with classical or quantized electromagnetic field. We prove that the absolute ground state energy, allowing for minimizing over all possible self-generated electromagnetic fields, is given by the non-magnetic Thomas-Fermi theory to leading order in the simultaneous Z → ∞, α → 0 limit if Zα2 ≤ κ for some universal κ, where α is the fine structure constant.
Original language | English |
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Journal | Communications in Mathematical Physics |
Volume | 294 |
Issue number | 1 |
Pages (from-to) | 229-249 |
ISSN | 0010-3616 |
DOIs | |
Publication status | Published - Jan 2009 |