Gas phase UV and IR absorption spectra of CxF2x+1CHO (x=1-4)

Y Hashikawa; M Kawasaki; RL Waterland; MD Hurley; JC Ball; TJ Wallington; Mads Peter Sulbæk Andersen; OJ Nielsen

doi:10.1016/j.jfluchem.2004.07.006

Gas phase UV and IR absorption spectra of CxF2x+1CHO (x=1-4)

Y Hashikawa, M Kawasaki, RL Waterland, MD Hurley, JC Ball, TJ Wallington, Mads Peter Sulbæk Andersen, OJ Nielsen

Department of Chemistry

17 Citations (Scopus)

Abstract

The UV and IR spectra of CxF2x+1 CHO (x = 1-4) were investigated using computational and experimental techniques. CxF2x+1CHO (x = 1-4) have broad UV absorption features centered at 300-310 nm. The maximum absorption cross-section increases significantly and shifts slightly to the red with increased length of the CxF2x+1 group: CF3CHO, 3.10 x 10(-20) (300 nm): C2F5CHO, 6.25 x 10(-20) (308 nm): C3F7CHO, 8.96 x 10(-20) (309 nm); and C4F9CHO, 10.9 x 10(-20) (309 nm). IR spectra for CxF2x+1CHO were recorded, calculated. and assigned. Results are discussed with respect to the literature data and to the atmospheric fate of CxF2x+1CHO. (C) 2004 Elsevier B.V. All rights reserved.

Original language	Undefined/Unknown
Journal	Journal of Fluorine Chemistry
Volume	125
Issue number	12
Pages (from-to)	1925-1932
Number of pages	8
ISSN	0022-1139
DOIs	https://doi.org/10.1016/j.jfluchem.2004.07.006
Publication status	Published - 1 Dec 2004

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10.1016/j.jfluchem.2004.07.006

Cite this

@article{17b4ad3d76b84a05b19f30bab496547d,

title = "Gas phase UV and IR absorption spectra of CxF2x+1CHO (x=1-4)",

abstract = "The UV and IR spectra of CxF2x+1 CHO (x = 1-4) were investigated using computational and experimental techniques. CxF2x+1CHO (x = 1-4) have broad UV absorption features centered at 300-310 nm. The maximum absorption cross-section increases significantly and shifts slightly to the red with increased length of the CxF2x+1 group: CF3CHO, 3.10 x 10(-20) (300 nm): C2F5CHO, 6.25 x 10(-20) (308 nm): C3F7CHO, 8.96 x 10(-20) (309 nm); and C4F9CHO, 10.9 x 10(-20) (309 nm). IR spectra for CxF2x+1CHO were recorded, calculated. and assigned. Results are discussed with respect to the literature data and to the atmospheric fate of CxF2x+1CHO. (C) 2004 Elsevier B.V. All rights reserved.",

author = "Y Hashikawa and M Kawasaki and RL Waterland and MD Hurley and JC Ball and TJ Wallington and Andersen, {Mads Peter Sulb{\ae}k} and OJ Nielsen",

year = "2004",

month = dec,

day = "1",

doi = "10.1016/j.jfluchem.2004.07.006",

language = "Udefineret/Ukendt",

volume = "125",

pages = "1925--1932",

journal = "Journal of Fluorine Chemistry",

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TY - JOUR

T1 - Gas phase UV and IR absorption spectra of CxF2x+1CHO (x=1-4)

AU - Hashikawa, Y

AU - Kawasaki, M

AU - Waterland, RL

AU - Hurley, MD

AU - Ball, JC

AU - Wallington, TJ

AU - Andersen, Mads Peter Sulbæk

AU - Nielsen, OJ

PY - 2004/12/1

Y1 - 2004/12/1

N2 - The UV and IR spectra of CxF2x+1 CHO (x = 1-4) were investigated using computational and experimental techniques. CxF2x+1CHO (x = 1-4) have broad UV absorption features centered at 300-310 nm. The maximum absorption cross-section increases significantly and shifts slightly to the red with increased length of the CxF2x+1 group: CF3CHO, 3.10 x 10(-20) (300 nm): C2F5CHO, 6.25 x 10(-20) (308 nm): C3F7CHO, 8.96 x 10(-20) (309 nm); and C4F9CHO, 10.9 x 10(-20) (309 nm). IR spectra for CxF2x+1CHO were recorded, calculated. and assigned. Results are discussed with respect to the literature data and to the atmospheric fate of CxF2x+1CHO. (C) 2004 Elsevier B.V. All rights reserved.

AB - The UV and IR spectra of CxF2x+1 CHO (x = 1-4) were investigated using computational and experimental techniques. CxF2x+1CHO (x = 1-4) have broad UV absorption features centered at 300-310 nm. The maximum absorption cross-section increases significantly and shifts slightly to the red with increased length of the CxF2x+1 group: CF3CHO, 3.10 x 10(-20) (300 nm): C2F5CHO, 6.25 x 10(-20) (308 nm): C3F7CHO, 8.96 x 10(-20) (309 nm); and C4F9CHO, 10.9 x 10(-20) (309 nm). IR spectra for CxF2x+1CHO were recorded, calculated. and assigned. Results are discussed with respect to the literature data and to the atmospheric fate of CxF2x+1CHO. (C) 2004 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.jfluchem.2004.07.006

DO - 10.1016/j.jfluchem.2004.07.006

M3 - Tidsskriftartikel

SN - 0022-1139

VL - 125

SP - 1925

EP - 1932

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 12

ER -