Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols

A. Lauridsen; Claus Cornett; S. B. Christensen

doi:10.3891/acta.chem.scand.45-0056

Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols

A. Lauridsen, Claus Cornett, S. B. Christensen

3 Citations (Scopus)

Abstract

alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.

Original language	Undefined/Unknown
Journal	Acta Chemica Scandinavica. Supplementum
Volume	45
Issue number	1
Pages (from-to)	56-62
Number of pages	7
ISSN	0065-1133
DOIs	https://doi.org/10.3891/acta.chem.scand.45-0056
Publication status	Published - 1991

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10.3891/acta.chem.scand.45-0056

Cite this

Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols. / Lauridsen, A.; Cornett, Claus ; Christensen, S. B.
In: Acta Chemica Scandinavica. Supplementum, Vol. 45, No. 1, 1991, p. 56-62.

Research output: Contribution to journal › Journal article › Research › peer-review

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abstract = "alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.",

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