Biomimetic triblock copolymer membranes: from aqueous solutions to solid supports

TY - JOUR

T1 - Biomimetic triblock copolymer membranes

T2 - from aqueous solutions to solid supports

AU - Alfredo, Gonzalez Perez

AU - Castelletto, V.

AU - Hamley, Ian W.

AU - Taboada, P.

PY - 2011/2/7

Y1 - 2011/2/7

N2 - In the present paper, we studied the preparation of biomimetic triblock copolymer (ABA) membranes in aqueous solution and their deposition into solid supports. The self-assembly structures of the ABA in aqueous solution was investigated by using optical microscopy, dynamic light scattering, electron microscopy (EM) and SAXS. Spherical and tubular polymersomes were found at the highest concentrations investigated. The mechanism of deposition on solid supports (mica and glass) was elucidated by using atomic force microscopy (AFM). The deposition results in the formation of a uniform defect-free membrane at suitable polymer concentrations.

AB - In the present paper, we studied the preparation of biomimetic triblock copolymer (ABA) membranes in aqueous solution and their deposition into solid supports. The self-assembly structures of the ABA in aqueous solution was investigated by using optical microscopy, dynamic light scattering, electron microscopy (EM) and SAXS. Spherical and tubular polymersomes were found at the highest concentrations investigated. The mechanism of deposition on solid supports (mica and glass) was elucidated by using atomic force microscopy (AFM). The deposition results in the formation of a uniform defect-free membrane at suitable polymer concentrations.

U2 - 10.1039/c0sm00711k

DO - 10.1039/c0sm00711k

M3 - Journal article

SN - 0959-9428

VL - 7

SP - 1129

EP - 1138

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 3

ER -