Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Jamie L. Manson; John A. Schlueter; Kerry E. Garrett; Paul A. Goddard; Tom Lancaster; Johannes S. Möller; Stephen J. Blundell; Andrew J. Steele; Isabel Franke; Francis L. Pratt; John Singleton; Jesper Bendix; Saul H. Lapidus; Marc Uhlarz; Oscar Ayala-Valenzuela; Ross D. McDonald; Mary Gurak; Christopher Baines

doi:10.1039/c6cc05873f

Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system

Jamie L. Manson^*, John A. Schlueter, Kerry E. Garrett, Paul A. Goddard, Tom Lancaster, Johannes S. Möller, Stephen J. Blundell, Andrew J. Steele, Isabel Franke, Francis L. Pratt, John Singleton, Jesper Bendix, Saul H. Lapidus, Marc Uhlarz, Oscar Ayala-Valenzuela, Ross D. McDonald, Mary Gurak, Christopher Baines

^*Corresponding author for this work

Department of Chemistry

4 Citations (Scopus)

Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)₂]²⁺ square lattices linked by MF₆ ^n- octahedra. In each, only the Cu²⁺ spins exhibit long-range magnetic order below 3.5 K (M = V⁴⁺) and 2.6 K (M = Ga³⁺). The V⁴⁺ spins remain disordered down to 0.5 K.

Original language	English
Journal	Chemical Communications
Volume	52
Issue number	85
Pages (from-to)	12653-12656
Number of pages	4
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c6cc05873f
Publication status	Published - 2016

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Manson, J. L., Schlueter, J. A., Garrett, K. E., Goddard, P. A., Lancaster, T., Möller, J. S., Blundell, S. J., Steele, A. J., Franke, I., Pratt, F. L., Singleton, J., Bendix, J., Lapidus, S. H., Uhlarz, M., Ayala-Valenzuela, O., McDonald, R. D., Gurak, M., & Baines, C. (2016). Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system. Chemical Communications, 52(85), 12653-12656. https://doi.org/10.1039/c6cc05873f

Manson, JL, Schlueter, JA, Garrett, KE, Goddard, PA, Lancaster, T, Möller, JS, Blundell, SJ, Steele, AJ, Franke, I, Pratt, FL, Singleton, J, Bendix, J, Lapidus, SH, Uhlarz, M, Ayala-Valenzuela, O, McDonald, RD, Gurak, M & Baines, C 2016, 'Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system', Chemical Communications, vol. 52, no. 85, pp. 12653-12656. https://doi.org/10.1039/c6cc05873f

@article{df0c6892fe3541b086215a3740b85e13,

title = "Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system",

abstract = "The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6 n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.",

author = "Manson, {Jamie L.} and Schlueter, {John A.} and Garrett, {Kerry E.} and Goddard, {Paul A.} and Tom Lancaster and M{\"o}ller, {Johannes S.} and Blundell, {Stephen J.} and Steele, {Andrew J.} and Isabel Franke and Pratt, {Francis L.} and John Singleton and Jesper Bendix and Lapidus, {Saul H.} and Marc Uhlarz and Oscar Ayala-Valenzuela and McDonald, {Ross D.} and Mary Gurak and Christopher Baines",

year = "2016",

doi = "10.1039/c6cc05873f",

language = "English",

volume = "52",

pages = "12653--12656",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "85",

}

TY - JOUR

T1 - Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1)

T2 - co-existence of ordered and disordered quantum spins in the V4+ system

AU - Manson, Jamie L.

AU - Schlueter, John A.

AU - Garrett, Kerry E.

AU - Goddard, Paul A.

AU - Lancaster, Tom

AU - Möller, Johannes S.

AU - Blundell, Stephen J.

AU - Steele, Andrew J.

AU - Franke, Isabel

AU - Pratt, Francis L.

AU - Singleton, John

AU - Bendix, Jesper

AU - Lapidus, Saul H.

AU - Uhlarz, Marc

AU - Ayala-Valenzuela, Oscar

AU - McDonald, Ross D.

AU - Gurak, Mary

AU - Baines, Christopher

PY - 2016

Y1 - 2016

N2 - The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6 n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

AB - The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6 n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

U2 - 10.1039/c6cc05873f

DO - 10.1039/c6cc05873f

M3 - Letter

C2 - 27713934

AN - SCOPUS:84992186936

SN - 1359-7345

VL - 52

SP - 12653

EP - 12656

JO - Chemical Communications

JF - Chemical Communications

IS - 85

ER -

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

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Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system