Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact

A. M. Toft; M. D. Hurley; T. J. Wallington; Mads Peter Sulbæk Andersen; Ole John Nielsen

doi:10.1016/j.cplett.2006.06.047

Atmospheric chemistry of C₄F₉O(CH₂)₃OC₄F₉ and CF₃CFHCF₂O (CH₂)₃OCF₃CFHCF₂: lifetimes, degradation products, and enviromental impact

A. M. Toft, M. D. Hurley, T. J. Wallington, Mads Peter Sulbæk Andersen, Ole John Nielsen

Department of Chemistry

4 Citations (Scopus)

Abstract

FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Journal	Chemical Physics Letters
Volume	427
Issue number	1-3
Pages (from-to)	41-46
Number of pages	6
ISSN	0009-2614
DOIs	https://doi.org/10.1016/j.cplett.2006.06.047
Publication status	Published - 2006

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10.1016/j.cplett.2006.06.047

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@article{612e0a6fd4fa40b6b35038928b8eb42b,

title = "Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact",

abstract = "FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.",

author = "Toft, {A. M.} and Hurley, {M. D.} and Wallington, {T. J.} and Andersen, {Mads Peter Sulb{\ae}k} and Nielsen, {Ole John}",

year = "2006",

doi = "10.1016/j.cplett.2006.06.047",

language = "English",

volume = "427",

pages = "41--46",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "1-3",

}

TY - JOUR

T1 - Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2

T2 - lifetimes, degradation products, and enviromental impact

AU - Toft, A. M.

AU - Hurley, M. D.

AU - Wallington, T. J.

AU - Andersen, Mads Peter Sulbæk

AU - Nielsen, Ole John

PY - 2006

Y1 - 2006

N2 - FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.

AB - FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.cplett.2006.06.047

DO - 10.1016/j.cplett.2006.06.047

M3 - Journal article

SN - 0009-2614

VL - 427

SP - 41

EP - 46

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact

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Atmospheric chemistry of C₄F₉O(CH₂)₃OC₄F₉ and CF₃CFHCF₂O (CH₂)₃OCF₃CFHCF₂: lifetimes, degradation products, and enviromental impact