Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

Y Hashikawa; M Kawasaki; Mads Peter Sulbæk Andersen; MD Hurley; TJ Wallington

doi:10.1016/j.cplett.2004.04.095

Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

Y Hashikawa, M Kawasaki, Mads Peter Sulbæk Andersen, MD Hurley, TJ Wallington

Department of Chemistry

6 Citations (Scopus)

Abstract

FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100-700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 +/- 0.05 and 0.47 +/- 0.05, respectively. Results are discussed with respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a. (C) 2004 Elsevier B.V. All rights reserved.

Original language	Undefined/Unknown
Journal	Chemical Physics Letters
Volume	391
Issue number	1-3
Pages (from-to)	165-169
Number of pages	5
ISSN	0009-2614
DOIs	https://doi.org/10.1016/j.cplett.2004.04.095
Publication status	Published - 11 Jun 2004

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10.1016/j.cplett.2004.04.095

Cite this

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title = "Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction",

abstract = "FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100-700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 +/- 0.05 and 0.47 +/- 0.05, respectively. Results are discussed with respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a. (C) 2004 Elsevier B.V. All rights reserved.",

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T1 - Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

AU - Hashikawa, Y

AU - Kawasaki, M

AU - Andersen, Mads Peter Sulbæk

AU - Hurley, MD

AU - Wallington, TJ

PY - 2004/6/11

Y1 - 2004/6/11

N2 - FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100-700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 +/- 0.05 and 0.47 +/- 0.05, respectively. Results are discussed with respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a. (C) 2004 Elsevier B.V. All rights reserved.

AB - FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100-700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 +/- 0.05 and 0.47 +/- 0.05, respectively. Results are discussed with respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a. (C) 2004 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.cplett.2004.04.095

DO - 10.1016/j.cplett.2004.04.095

M3 - Tidsskriftartikel

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SP - 165

EP - 169

JO - Chemical Physics Letters

JF - Chemical Physics Letters

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