TY - JOUR
T1 - Ancient melt depletion overprinted by young carbonatitic metasomatism in the New Zealand lithospheric mantle
AU - Scott, James M.
AU - Hodgkinson, A.
AU - Palin, J.M.
AU - Waight, Tod Earle
AU - van der Meer, Quinten
AU - Cooper, A.F.
PY - 2014/1
Y1 - 2014/1
N2 - Spinel facies dunite, harzburgite, lherzolite and wehrlite mantle xenoliths from a cluster of Miocene volcanoes in southern New Zealand preserve evidence of the complex evolution of the underlying continental mantle lithosphere. Spinel Cr# records melt extraction with some values indicative of near complete removal of clinopyroxene. LREE-enriched, low Ti/Eu and low Al2O3 clinopyroxene and rare F-, LREE-rich apatite indicates subsequent interaction between peridotite and a metasomatising carbonatitic melt. The clearest metasomatic signature occurs in the formerly highly depleted samples because there was little or no pre-existing clinopyroxene to dilute the carbonatite signature. For the same reason, the isotopic character of the metasomatising agent is best observed in the formerly highly depleted peridotites (87Sr/86Sr = 0.7028-0.7031; 143Nd/144Nd = 0.5129; 206Pb/204Pb = 20.2-20.3). These isotope ratios are very close to, but slightly less radiogenic than, the HIMU end-member mantle reservoir. Nd isotope data imply carbonatite metasomatism occurred within the last several hundred million years, with ubiquitous pyroxene core-to-rim Al diffusion zoning indicating that it must pre-date cooling of the lithospheric mantle following Late Cretaceous-Eocene rifting of Zealandia from Gondwana. Metasomatism was significantly younger than ancient Re-depletion ages of ~2 Ga and shows that decoupling of peridotite isotope systems has occurred.
AB - Spinel facies dunite, harzburgite, lherzolite and wehrlite mantle xenoliths from a cluster of Miocene volcanoes in southern New Zealand preserve evidence of the complex evolution of the underlying continental mantle lithosphere. Spinel Cr# records melt extraction with some values indicative of near complete removal of clinopyroxene. LREE-enriched, low Ti/Eu and low Al2O3 clinopyroxene and rare F-, LREE-rich apatite indicates subsequent interaction between peridotite and a metasomatising carbonatitic melt. The clearest metasomatic signature occurs in the formerly highly depleted samples because there was little or no pre-existing clinopyroxene to dilute the carbonatite signature. For the same reason, the isotopic character of the metasomatising agent is best observed in the formerly highly depleted peridotites (87Sr/86Sr = 0.7028-0.7031; 143Nd/144Nd = 0.5129; 206Pb/204Pb = 20.2-20.3). These isotope ratios are very close to, but slightly less radiogenic than, the HIMU end-member mantle reservoir. Nd isotope data imply carbonatite metasomatism occurred within the last several hundred million years, with ubiquitous pyroxene core-to-rim Al diffusion zoning indicating that it must pre-date cooling of the lithospheric mantle following Late Cretaceous-Eocene rifting of Zealandia from Gondwana. Metasomatism was significantly younger than ancient Re-depletion ages of ~2 Ga and shows that decoupling of peridotite isotope systems has occurred.
U2 - 10.1007/s00410-014-0963-0
DO - 10.1007/s00410-014-0963-0
M3 - Journal article
SN - 0010-7999
VL - 167
JO - Contributions to Mineralogy and Petrology
JF - Contributions to Mineralogy and Petrology
M1 - 963
ER -