A new high precision determination of the atmospheric Ne-21 abundance

TY - JOUR

T1 - A new high precision determination of the atmospheric Ne-21 abundance

AU - Wielandt, Daniel

AU - Storey, Michael

PY - 2019/3/1

Y1 - 2019/3/1

N2 - We have carried out a series of precise Ne-isotope measurements of atmospheric Ne-separates on a state-of-the-art high mass resolution Thermo-Fisher Helix MC Plus Noble Gas Mass Spectrometer. We used a combination of static and dynamic configurations and techniques that allow us to minimize possible analytical artifacts related to isobaric interferences, magnet hysteresis and detector efficiencies. All Ne-isotope signals were measured at high ion beam intensities on accurately intercalibrated Faraday collectors connected to 1012 and 1013 ohm amplifiers, providing linearity and optimal dynamic range and signal/noise ratio. Following consideration of known possible sources of interference, and mass discrimination correction assuming an atmospheric 22Ne/20Ne ratio of 0.102, we derive the relative mass fractionation corrected 21Ne abundance in the terrestrial atmosphere, allowing us to determine a new 21Ne/20Ne ratio of 0.0029577 ± 14. This value is significantly more precise than any previously reported determinations, with implications for atmospheric models and standardization protocols, and potential improvements for the precision and accuracy of terrestrial cosmogenic neon exposure dating, in particular for young exposure ages.

AB - We have carried out a series of precise Ne-isotope measurements of atmospheric Ne-separates on a state-of-the-art high mass resolution Thermo-Fisher Helix MC Plus Noble Gas Mass Spectrometer. We used a combination of static and dynamic configurations and techniques that allow us to minimize possible analytical artifacts related to isobaric interferences, magnet hysteresis and detector efficiencies. All Ne-isotope signals were measured at high ion beam intensities on accurately intercalibrated Faraday collectors connected to 1012 and 1013 ohm amplifiers, providing linearity and optimal dynamic range and signal/noise ratio. Following consideration of known possible sources of interference, and mass discrimination correction assuming an atmospheric 22Ne/20Ne ratio of 0.102, we derive the relative mass fractionation corrected 21Ne abundance in the terrestrial atmosphere, allowing us to determine a new 21Ne/20Ne ratio of 0.0029577 ± 14. This value is significantly more precise than any previously reported determinations, with implications for atmospheric models and standardization protocols, and potential improvements for the precision and accuracy of terrestrial cosmogenic neon exposure dating, in particular for young exposure ages.

U2 - 10.1039/c8ja00336j

DO - 10.1039/c8ja00336j

M3 - Journal article

SN - 0267-9477

VL - 34

SP - 535

EP - 549

JO - Journal of Analytical Atomic Spectrometry

JF - Journal of Analytical Atomic Spectrometry

IS - 3

ER -