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The synthesis of mono- and diacetyl-9
H
-fluorenes. Reactivity and selectivity in the Lewis acid catalyzed Friedel-Crafts acetylation of 9
H
-fluorene
Salam J. J. Titinchi, Fadhil S. Kamounah, Hanna S. Abbo,
Ole Hammerich
Kemisk Institut
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H
-fluorenes. Reactivity and selectivity in the Lewis acid catalyzed Friedel-Crafts acetylation of 9
H
-fluorene'. Sammen danner de et unikt fingeraftryk.
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Keyphrases
9H-fluorene
100%
Diacetyl
100%
Friedel-Crafts Acylation
100%
Aluminum Chloride
14%
Carbon Disulfide
14%
Nitromethane
14%
Selectivity Patterns
14%
Reflux
7%
Acetylation
7%
Dichloroethane
7%
Monoacetylation
7%
Product Distribution
7%
Kinetically Controlled
7%
Chloroalkanes
7%
Lewis Acid Catalyst
7%
Diacetylation
7%
Gibbs Free Energy
7%
Solvent Polarity
7%
1H NMR Spectra
7%
B3LYP
7%
B3LYP/6-31G
7%
Percentage Yield
7%
Physicochemical Methods
7%
Acetyl Chloride
7%
Chemistry
Fluorene
100%
Acetylation
100%
Acetyl
28%
Nitromethane
14%
Carbon Disulfide
14%
Gibbs Free Energy
7%
Diacetylation
7%
DFT-B3LYP Calculation
7%
1H NMR Spectrum
7%
Acetyl Chloride
7%
Acid Catalyst
7%
solvent polarity
7%
Chloroalkane
7%