Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen

Wei Li; Alba Silipo; Lotte Bettina Andersen Gersby; Mari-Anne Newman; Antonio Molinaro; Biao Yu

doi:10.1002/anie.201610680

Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen

Wei Li, Alba Silipo, Lotte Bettina Andersen Gersby, Mari-Anne Newman, Antonio Molinaro, Biao Yu

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14 Citationer (Scopus)

Abstract

The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.

Originalsprog	Engelsk
Tidsskrift	Angewandte Chemie International Edition
Vol/bind	56
Udgave nummer	8
Sider (fra-til)	2092-2096
Antal sider	5
ISSN	1433-7851
DOI	https://doi.org/10.1002/anie.201610680
Status	Udgivet - 13 feb. 2017

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10.1002/anie.201610680

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AU - Li, Wei

AU - Silipo, Alba

AU - Gersby, Lotte Bettina Andersen

AU - Newman, Mari-Anne

AU - Molinaro, Antonio

AU - Yu, Biao

PY - 2017/2/13

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AB - The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.

KW - Journal Article

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Synthesis of bradyrhizose oligosaccharides relevant to the Bradyrhizobium O-antigen

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