Subphthalocyanine-radiaannulene scaffold – a multi-electron acceptor and strong chromophore

Henriette Schjøtt Lissau; Cecilie Lindholm Andersen; Freja Eilsø Storm; Marco Santella; Ole Hammerich; Thorsten Hansen; Kurt Valentin Mikkelsen; Mogens Brøndsted Nielsen

doi:10.1039/C8CC00028J

Subphthalocyanine-radiaannulene scaffold – a multi-electron acceptor and strong chromophore

Henriette Schjøtt Lissau, Cecilie Lindholm Andersen, Freja Eilsø Storm, Marco Santella, Ole Hammerich, Thorsten Hansen, Kurt Valentin Mikkelsen, Mogens Brøndsted Nielsen

Kemisk Institut

3 Citationer (Scopus)

Abstract

Two subphthalocyanine (SubPc) units and a perethynylated, alkyne-expanded radiaannulene (RA) were fused together by a four-fold Sonogashira reaction to give a compound exhibiting: (i) four reversible one-electron reductions, the first signalling good acceptor strength of the RA core itself, while the following three are a consequence of the entire scaffold, and (ii) intense light absorption that spans a remarkably broad region.

Originalsprog	Engelsk
Artikelnummer	54
Tidsskrift	Chemical Communications
Vol/bind	22
Sider (fra-til)	2763-2766
Antal sider	4
ISSN	1359-7345
DOI	https://doi.org/10.1039/C8CC00028J
Status	Udgivet - 2018

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10.1039/C8CC00028J

Citationsformater

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title = "Subphthalocyanine-radiaannulene scaffold – a multi-electron acceptor and strong chromophore",

abstract = "Two subphthalocyanine (SubPc) units and a perethynylated, alkyne-expanded radiaannulene (RA) were fused together by a four-fold Sonogashira reaction to give a compound exhibiting: (i) four reversible one-electron reductions, the first signalling good acceptor strength of the RA core itself, while the following three are a consequence of the entire scaffold, and (ii) intense light absorption that spans a remarkably broad region.",

author = "Lissau, {Henriette Schj{\o}tt} and Andersen, {Cecilie Lindholm} and Storm, {Freja Eils{\o}} and Marco Santella and Ole Hammerich and Thorsten Hansen and Mikkelsen, {Kurt Valentin} and Nielsen, {Mogens Br{\o}ndsted}",

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doi = "10.1039/C8CC00028J",

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journal = "Chemical Communications",

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TY - JOUR

T1 - Subphthalocyanine-radiaannulene scaffold – a multi-electron acceptor and strong chromophore

AU - Lissau, Henriette Schjøtt

AU - Andersen, Cecilie Lindholm

AU - Storm, Freja Eilsø

AU - Santella, Marco

AU - Hammerich, Ole

AU - Hansen, Thorsten

AU - Mikkelsen, Kurt Valentin

AU - Nielsen, Mogens Brøndsted

PY - 2018

Y1 - 2018

N2 - Two subphthalocyanine (SubPc) units and a perethynylated, alkyne-expanded radiaannulene (RA) were fused together by a four-fold Sonogashira reaction to give a compound exhibiting: (i) four reversible one-electron reductions, the first signalling good acceptor strength of the RA core itself, while the following three are a consequence of the entire scaffold, and (ii) intense light absorption that spans a remarkably broad region.

AB - Two subphthalocyanine (SubPc) units and a perethynylated, alkyne-expanded radiaannulene (RA) were fused together by a four-fold Sonogashira reaction to give a compound exhibiting: (i) four reversible one-electron reductions, the first signalling good acceptor strength of the RA core itself, while the following three are a consequence of the entire scaffold, and (ii) intense light absorption that spans a remarkably broad region.

U2 - 10.1039/C8CC00028J

DO - 10.1039/C8CC00028J

M3 - Journal article

SN - 1359-7345

VL - 22

SP - 2763

EP - 2766

JO - Chemical Communications

JF - Chemical Communications

M1 - 54

ER -

Subphthalocyanine-radiaannulene scaffold – a multi-electron acceptor and strong chromophore

Abstract

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