Reduction of nitro compounds and related substrates

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Abstract

The electrochemical reduction of nitro compounds played an important role in the development of organic electrochemistry in the early period around 1900 [1]. For example, it was studies of the stepwise reduction of nitrobenzene that originally led Haber [2] to realize the importance of the potential of the working electrode in electrochemistry and to establish the redox relationship between nitrobenzene, nitrosobenzene, phenylhydroxylamine, aniline, p-hydroxyaniline, azoxybenzene, azobenzene, hydrazobenzene, and benzidine [2,3]. The essential parts are reproduced in Scheme 30.1.

OriginalsprogEngelsk
TitelOrganic electrochemistry : revised and expanded
RedaktørerOle Hammerich, Bernd Speiser
Antal sider52
ForlagCRC Press
Publikationsdato1 jan. 2015
Udgave5.
Sider1149-1200
Kapitel30
ISBN (Trykt)978-1-4200-8401-6
ISBN (Elektronisk)978-1-4200-8402-3
DOI
StatusUdgivet - 1 jan. 2015

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