Raman and magnetic susceptibility studies of hexagonal elpasolite Cs2NaAlF6:Cr3+

L. P. Sosman; F. Yokaichiya; H. N. Bordallo

doi:10.1016/j.jmmm.2009.01.026

Raman and magnetic susceptibility studies of hexagonal elpasolite Cs₂NaAlF₆:Cr³⁺

L. P. Sosman^*, F. Yokaichiya, H. N. Bordallo

^*Corresponding author af dette arbejde

5 Citationer (Scopus)

Abstract

Polarized Raman scattering spectra of distorted R over(3 m, -) elpasolites Cs₂NaAlF₆ with a Cr³⁺ content of 0.1, 0.5 and 3.0 at% have been studied at both room temperature and 16 K. A shoulder located near the very intense band assigned to the AlF₆^3- A_1g mode indicates that the guest ion causes only small perturbations to the host lattice. Magnetic susceptibility measurements performed on the 0.1, 0.5, 3, 10 and 50 at% samples show that for particular concentrations the Cr³⁺ ions are not isolated, but participate to inter and/or intra-cluster magnetic exchange.

Originalsprog	Engelsk
Tidsskrift	Journal of Magnetism and Magnetic Materials
Vol/bind	321
Udgave nummer	14
Sider (fra-til)	2210-2215
Antal sider	6
ISSN	0304-8853
DOI	https://doi.org/10.1016/j.jmmm.2009.01.026
Status	Udgivet - 1 jul. 2009
Udgivet eksternt	Ja

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Citationsformater

@article{1846ee02b1464ec592a35e09958340b4,

title = "Raman and magnetic susceptibility studies of hexagonal elpasolite Cs2NaAlF6:Cr3+",

abstract = "Polarized Raman scattering spectra of distorted R over(3 m, -) elpasolites Cs2NaAlF6 with a Cr3+ content of 0.1, 0.5 and 3.0 at% have been studied at both room temperature and 16 K. A shoulder located near the very intense band assigned to the AlF63- A1g mode indicates that the guest ion causes only small perturbations to the host lattice. Magnetic susceptibility measurements performed on the 0.1, 0.5, 3, 10 and 50 at% samples show that for particular concentrations the Cr3+ ions are not isolated, but participate to inter and/or intra-cluster magnetic exchange.",

keywords = "Chromium doping, Elpasolite, Magnetic correlation, Polarized Raman",

author = "Sosman, {L. P.} and F. Yokaichiya and Bordallo, {H. N.}",

year = "2009",

month = jul,

day = "1",

doi = "10.1016/j.jmmm.2009.01.026",

language = "English",

volume = "321",

pages = "2210--2215",

journal = "Journal of Magnetism and Magnetic Materials",

issn = "0304-8853",

publisher = "Elsevier BV * North-Holland",

number = "14",

}

TY - JOUR

T1 - Raman and magnetic susceptibility studies of hexagonal elpasolite Cs2NaAlF6:Cr3+

AU - Sosman, L. P.

AU - Yokaichiya, F.

AU - Bordallo, H. N.

PY - 2009/7/1

Y1 - 2009/7/1

N2 - Polarized Raman scattering spectra of distorted R over(3 m, -) elpasolites Cs2NaAlF6 with a Cr3+ content of 0.1, 0.5 and 3.0 at% have been studied at both room temperature and 16 K. A shoulder located near the very intense band assigned to the AlF63- A1g mode indicates that the guest ion causes only small perturbations to the host lattice. Magnetic susceptibility measurements performed on the 0.1, 0.5, 3, 10 and 50 at% samples show that for particular concentrations the Cr3+ ions are not isolated, but participate to inter and/or intra-cluster magnetic exchange.

AB - Polarized Raman scattering spectra of distorted R over(3 m, -) elpasolites Cs2NaAlF6 with a Cr3+ content of 0.1, 0.5 and 3.0 at% have been studied at both room temperature and 16 K. A shoulder located near the very intense band assigned to the AlF63- A1g mode indicates that the guest ion causes only small perturbations to the host lattice. Magnetic susceptibility measurements performed on the 0.1, 0.5, 3, 10 and 50 at% samples show that for particular concentrations the Cr3+ ions are not isolated, but participate to inter and/or intra-cluster magnetic exchange.

KW - Chromium doping

KW - Elpasolite

KW - Magnetic correlation

KW - Polarized Raman

UR - http://www.scopus.com/inward/record.url?scp=65349106448&partnerID=8YFLogxK

U2 - 10.1016/j.jmmm.2009.01.026

DO - 10.1016/j.jmmm.2009.01.026

M3 - Journal article

AN - SCOPUS:65349106448

SN - 0304-8853

VL - 321

SP - 2210

EP - 2215

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

IS - 14

ER -