New accurate compression data for γ-Fe2SiO4

Fabrizio Nestola, Tiziana Boffa-Ballaran, Monika Koch-Müller, Tonci Balic Zunic, Michael Taran, Lars Arnskov Olsen, Francesco Princivalle, Luciano Secco, Lars Lundegaard

16 Citationer (Scopus)

Abstract

The equation of state for γ-Fe2SiO4 was determined by single-crystal X-ray diffraction up to 10.2GPa at room temperature. The pressure-volume data, measured at 10 different pressures, do not show any evidence of a phase transformation and were fit by a third-order Birch-Murnaghan equation of state. The following coefficients were refined simultaneously: V0=559.44(6)Å3, KT0=187.3(1.7)GPa, and K'=5.5(4). This result implies that the Mg/Fe substitution along the γ-Fo-Fa join does not significantly affect the bulk modulus. The sample shows higher K' than other compositions along the Fo-Fa join, which generally have K'∼4. Based on our results we can calculate the sound bulk velocity of γ-Fe2SiO4 up to the pressures of the Transition Zone. Due to the larger K' of γ-Fe2SiO4, the difference in bulk sound velocity between the two end-members decreases with increasing pressure.

OriginalsprogEngelsk
TidsskriftPhysics of the Earth and Planetary Interiors
Vol/bind183
Udgave nummer3-4
Sider (fra-til)421-425
Antal sider5
ISSN0031-9201
DOI
StatusUdgivet - 1 dec. 2010

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