Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework

Zhongming Wei; Tim Hansen; Marco Santella; Xintai Wang; Christian Richard Parker; Xingbin Jiang; Tao Li; Magni Glyvradal; Karsten Stein Jennum; Emil Glibstrup; Nicolas Emile Bovet; Xiaowei Wang; Wenping Hu; Gemma C. Solomon; Mogens Brøndsted Nielsen; Xiaohui Qiu; Thomas Bjørnholm; Kasper Nørgaard; Bo Wegge Laursen

doi:10.1002/adfm.201404388

Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework

Zhongming Wei, Tim Hansen, Marco Santella, Xintai Wang, Christian Richard Parker, Xingbin Jiang, Tao Li, Magni Glyvradal, Karsten Stein Jennum, Emil Glibstrup, Nicolas Emile Bovet, Xiaowei Wang, Wenping Hu, Gemma C. Solomon, Mogens Brøndsted Nielsen, Xiaohui Qiu, Thomas Bjørnholm, Kasper Nørgaard^*, Bo Wegge Laursen

^*Corresponding author af dette arbejde

Kemisk Institut

18 Citationer (Scopus)

Abstract

Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO-LUMO energy gaps. OPE3, OPE3-DTF, and OPE3-tetrathiafulvalene (TTF) can form good self-assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe-atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3-TTF > OPE3-DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero-bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.

Originalsprog	Engelsk
Tidsskrift	Advanced Functional Materials
Vol/bind	25
Udgave nummer	11
Sider (fra-til)	1700-1708
Antal sider	9
ISSN	1616-301X
DOI	https://doi.org/10.1002/adfm.201404388
Status	Udgivet - 21 jan. 2015

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10.1002/adfm.201404388

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Wei, Z., Hansen, T., Santella, M., Wang, X., Parker, C. R., Jiang, X., Li, T., Glyvradal, M., Jennum, K. S., Glibstrup, E., Bovet, N. E., Wang, X., Hu, W., Solomon, G. C., Nielsen, M. B., Qiu, X., Bjørnholm, T., Nørgaard, K., & Laursen, B. W. (2015). Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework. Advanced Functional Materials, 25(11), 1700-1708. https://doi.org/10.1002/adfm.201404388

Wei, Z, Hansen, T, Santella, M, Wang, X, Parker, CR, Jiang, X, Li, T, Glyvradal, M, Jennum, KS, Glibstrup, E, Bovet, NE, Wang, X, Hu, W, Solomon, GC , Nielsen, MB, Qiu, X, Bjørnholm, T, Nørgaard, K & Laursen, BW 2015, 'Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework', Advanced Functional Materials, bind 25, nr. 11, s. 1700-1708. https://doi.org/10.1002/adfm.201404388

@article{47487d15ea9040e58ad614db34c5b2ef,

title = "Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework",

abstract = "Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO-LUMO energy gaps. OPE3, OPE3-DTF, and OPE3-tetrathiafulvalene (TTF) can form good self-assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe-atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3-TTF > OPE3-DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero-bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.",

keywords = "Atomic force microscopy, Cruciform, Dithiofulvalene, Molecular electronics, Oligo(phenylene ethynylene)",

author = "Zhongming Wei and Tim Hansen and Marco Santella and Xintai Wang and Parker, {Christian Richard} and Xingbin Jiang and Tao Li and Magni Glyvradal and Jennum, {Karsten Stein} and Emil Glibstrup and Bovet, {Nicolas Emile} and Xiaowei Wang and Wenping Hu and Solomon, {Gemma C.} and Nielsen, {Mogens Br{\o}ndsted} and Xiaohui Qiu and Thomas Bj{\o}rnholm and Kasper N{\o}rgaard and Laursen, {Bo Wegge}",

year = "2015",

month = jan,

day = "21",

doi = "10.1002/adfm.201404388",

language = "English",

volume = "25",

pages = "1700--1708",

journal = "Advanced Functional Materials",

issn = "1616-301X",

publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",

number = "11",

}

TY - JOUR

T1 - Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework

AU - Wei, Zhongming

AU - Hansen, Tim

AU - Santella, Marco

AU - Wang, Xintai

AU - Parker, Christian Richard

AU - Jiang, Xingbin

AU - Li, Tao

AU - Glyvradal, Magni

AU - Jennum, Karsten Stein

AU - Glibstrup, Emil

AU - Bovet, Nicolas Emile

AU - Wang, Xiaowei

AU - Hu, Wenping

AU - Solomon, Gemma C.

AU - Nielsen, Mogens Brøndsted

AU - Qiu, Xiaohui

AU - Bjørnholm, Thomas

AU - Nørgaard, Kasper

AU - Laursen, Bo Wegge

PY - 2015/1/21

Y1 - 2015/1/21

N2 - Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO-LUMO energy gaps. OPE3, OPE3-DTF, and OPE3-tetrathiafulvalene (TTF) can form good self-assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe-atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3-TTF > OPE3-DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero-bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.

AB - Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO-LUMO energy gaps. OPE3, OPE3-DTF, and OPE3-tetrathiafulvalene (TTF) can form good self-assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe-atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3-TTF > OPE3-DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero-bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.

KW - Atomic force microscopy

KW - Cruciform

KW - Dithiofulvalene

KW - Molecular electronics

KW - Oligo(phenylene ethynylene)

U2 - 10.1002/adfm.201404388

DO - 10.1002/adfm.201404388

M3 - Journal article

SN - 1616-301X

VL - 25

SP - 1700

EP - 1708

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 11

ER -

Molecular heterojunctions of oligo(phenylene ethynylene)s with linear to cruciform framework

Abstract

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