Magnesium and nickel(II) furan-2,5-dicarboxylate

Magnus Schau-Magnussen; Yury Y. Gorbanev; Soren Kegnaes; Anders Riisager

doi:10.1107/S0108270111036535

Magnesium and nickel(II) furan-2,5-dicarboxylate

Magnus Schau-Magnussen, Yury Y. Gorbanev, Soren Kegnaes, Anders Riisager

Kemisk Institut

4 Citationer (Scopus)

Abstract

The salts hexaaquamagnesium furan-2,5-dicarboxylate, [Mg(H2O)(6)](C6H2O5), (I), and hexaaquanickel furan-2,5-dicarboxylate, [Ni(H2O)(6)](C6H2O5), (II), provide the first crystallographic characterization of the furan-2,5-dicarboxylate dianion. Both structures exhibit extensive three-dimensional hydrogen-bonding networks between the octahedral coordinated hexaaquametal(II) ions and the dicarboxylate anions. Although the two structures are not isomorphous, they contain essentially identical two-dimensional slabs. The distinction between the structures is that these slabs are related by translation in (II), whereas adjacent slabs in (I) are reflected relative to each other by the action of a glide plane. The reflection occurs so that the local contacts between slabs are not changed, and thus the hydrogen-bond networks are identical except for the orientation of the water molecules at the interface between slabs.

Originalsprog	Engelsk
Tidsskrift	Acta Crystallographica. Section C: Crystal Structure Communications
Vol/bind	67
Udgave nummer	10
Sider (fra-til)	M327-M330
Antal sider	4
ISSN	0108-2701
DOI	https://doi.org/10.1107/S0108270111036535
Status	Udgivet - okt. 2011

Adgang til dokumentet

10.1107/S0108270111036535

Citationsformater

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title = "Magnesium and nickel(II) furan-2,5-dicarboxylate",

abstract = "The salts hexaaquamagnesium furan-2,5-dicarboxylate, [Mg(H2O)(6)](C6H2O5), (I), and hexaaquanickel furan-2,5-dicarboxylate, [Ni(H2O)(6)](C6H2O5), (II), provide the first crystallographic characterization of the furan-2,5-dicarboxylate dianion. Both structures exhibit extensive three-dimensional hydrogen-bonding networks between the octahedral coordinated hexaaquametal(II) ions and the dicarboxylate anions. Although the two structures are not isomorphous, they contain essentially identical two-dimensional slabs. The distinction between the structures is that these slabs are related by translation in (II), whereas adjacent slabs in (I) are reflected relative to each other by the action of a glide plane. The reflection occurs so that the local contacts between slabs are not changed, and thus the hydrogen-bond networks are identical except for the orientation of the water molecules at the interface between slabs.",

author = "Magnus Schau-Magnussen and Gorbanev, {Yury Y.} and Soren Kegnaes and Anders Riisager",

year = "2011",

month = oct,

doi = "10.1107/S0108270111036535",

language = "English",

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pages = "M327--M330",

journal = "Acta crystallographica. Section C, Structural chemistry",

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TY - JOUR

T1 - Magnesium and nickel(II) furan-2,5-dicarboxylate

AU - Schau-Magnussen, Magnus

AU - Gorbanev, Yury Y.

AU - Kegnaes, Soren

AU - Riisager, Anders

PY - 2011/10

Y1 - 2011/10

N2 - The salts hexaaquamagnesium furan-2,5-dicarboxylate, [Mg(H2O)(6)](C6H2O5), (I), and hexaaquanickel furan-2,5-dicarboxylate, [Ni(H2O)(6)](C6H2O5), (II), provide the first crystallographic characterization of the furan-2,5-dicarboxylate dianion. Both structures exhibit extensive three-dimensional hydrogen-bonding networks between the octahedral coordinated hexaaquametal(II) ions and the dicarboxylate anions. Although the two structures are not isomorphous, they contain essentially identical two-dimensional slabs. The distinction between the structures is that these slabs are related by translation in (II), whereas adjacent slabs in (I) are reflected relative to each other by the action of a glide plane. The reflection occurs so that the local contacts between slabs are not changed, and thus the hydrogen-bond networks are identical except for the orientation of the water molecules at the interface between slabs.

AB - The salts hexaaquamagnesium furan-2,5-dicarboxylate, [Mg(H2O)(6)](C6H2O5), (I), and hexaaquanickel furan-2,5-dicarboxylate, [Ni(H2O)(6)](C6H2O5), (II), provide the first crystallographic characterization of the furan-2,5-dicarboxylate dianion. Both structures exhibit extensive three-dimensional hydrogen-bonding networks between the octahedral coordinated hexaaquametal(II) ions and the dicarboxylate anions. Although the two structures are not isomorphous, they contain essentially identical two-dimensional slabs. The distinction between the structures is that these slabs are related by translation in (II), whereas adjacent slabs in (I) are reflected relative to each other by the action of a glide plane. The reflection occurs so that the local contacts between slabs are not changed, and thus the hydrogen-bond networks are identical except for the orientation of the water molecules at the interface between slabs.

U2 - 10.1107/S0108270111036535

DO - 10.1107/S0108270111036535

M3 - Journal article

C2 - 21979968

SN - 2053-2296

VL - 67

SP - M327-M330

JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

IS - 10

ER -