Lillianites and andorites: new life for the oldest homologous series of sulfosalts

Emil Makovicky, Dan Topa

13 Citationer (Scopus)

Abstract

The current state of the lillianite homologous series is presented, with its two branches the lillianite branch of the predominantly Pb-Bi-Ag sulfosalts and the andorite branch of predominantly Pb-Sb-Ag sulfosalts. Both the natural and synthetic members are discussed, especially from the structural and
compositional point of view and the related, chemically distinct and structurally more complicated members of the series are described. A number of new published, or hitherto unpublished observations is given, together with fairly exhaustive tables of data. Relationships between the complex structures of
different ‘andorite’ species and principal structural features of ‘oversubstituted’ As-Sb and Bi-Sb species are discussed. Contrary to many studies of this subject, synthetic phases form an integral part of the paper. It is concluded that research in this long-known homologous series still supplies new interesting phases, especially in the fields of synthetic products and in its andorite branch.
OriginalsprogEngelsk
TidsskriftMineralogical Magazine
Vol/bind78
Udgave nummer2
Sider (fra-til)387-414
Antal sider29
ISSN0026-461X
DOI
StatusUdgivet - apr. 2014

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