Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene

Mads Peter Sulbæk Andersen; DA Ponomarev; OJ Nielsen; MD Hurley; TJ Wallington

Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene

Mads Peter Sulbæk Andersen, DA Ponomarev, OJ Nielsen, MD Hurley, TJ Wallington

Kemisk Institut

11 Citationer (Scopus)

Abstract

Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.

Originalsprog	Udefineret/Ukendt
Tidsskrift	Chemical Physics Letters
Vol/bind	350
Udgave nummer	5-6
Sider (fra-til)	423-426
Antal sider	4
ISSN	0009-2614
Status	Udgivet - 28 dec. 2001

Citationsformater

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abstract = "Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.",

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volume = "350",

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TY - JOUR

T1 - Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene

AU - Andersen, Mads Peter Sulbæk

AU - Ponomarev, DA

AU - Nielsen, OJ

AU - Hurley, MD

AU - Wallington, TJ

PY - 2001/12/28

Y1 - 2001/12/28

N2 - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.

AB - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.

M3 - Tidsskriftartikel

SN - 0009-2614

VL - 350

SP - 423

EP - 426

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5-6

ER -