TY - JOUR
T1 - Ferrimagnetism and spin excitation in a Ni–Mn partially inverted spinel prepared using a modified polymeric precursor method
AU - Ferreira, R.A.
AU - Tedesco, Julio Cesar G.
AU - Birk, Jonas Okkels
AU - Kalceff, W.
AU - Yokaichiya, F.
AU - Rasmussen, Nina
AU - Peña, Octavio
AU - Henry, Paul F.
AU - Simeoni, Giovanna G.
AU - Nunes Bordallo, Heloisa
AU - Lisboa-Filho, Paulo N.
PY - 2014/7/15
Y1 - 2014/7/15
N2 - We demonstrate that a Ni-Mn oxide partially inverted spinel (Ni 1-νMnν)[NiνMn2-ν]O 4 having inversion degree ν 0.8 and produced by a modified polymeric precursor method exhibits behaviour previously reported only in monophased samples. The structure of the specimen was determined using Rietveld analysis of X-ray and neutron powder diffraction data, showing that at room temperature the material crystallizes in the Fd3̄m space group with a lattice constant a = 8.392 Å. Combining magnetization measurements with neutron powder diffraction, we show that the magnetic structure of this spinel is associated with the interplay between the ferromagnetic and antiferromagnetic lattices which coexist due to the cations' presence on both tetrahedral and octahedral sites. Our analysis of the neutron diffraction data confirms the postulated magnetic structure involving a star-like moment arrangement, arising from competition for the B (octahedral) spinel sites by the Ni and Mn cations. Finally, we show that strong magnetic fluctuations are observed in the inelastic neutron scattering data.
AB - We demonstrate that a Ni-Mn oxide partially inverted spinel (Ni 1-νMnν)[NiνMn2-ν]O 4 having inversion degree ν 0.8 and produced by a modified polymeric precursor method exhibits behaviour previously reported only in monophased samples. The structure of the specimen was determined using Rietveld analysis of X-ray and neutron powder diffraction data, showing that at room temperature the material crystallizes in the Fd3̄m space group with a lattice constant a = 8.392 Å. Combining magnetization measurements with neutron powder diffraction, we show that the magnetic structure of this spinel is associated with the interplay between the ferromagnetic and antiferromagnetic lattices which coexist due to the cations' presence on both tetrahedral and octahedral sites. Our analysis of the neutron diffraction data confirms the postulated magnetic structure involving a star-like moment arrangement, arising from competition for the B (octahedral) spinel sites by the Ni and Mn cations. Finally, we show that strong magnetic fluctuations are observed in the inelastic neutron scattering data.
U2 - 10.1016/j.matchemphys.2014.02.042
DO - 10.1016/j.matchemphys.2014.02.042
M3 - Journal article
SN - 0254-0584
VL - 146
SP - 58
EP - 64
JO - Materials Chemistry and Physics
JF - Materials Chemistry and Physics
IS - 1-2
ER -