Exploring endoperoxides as a new entry for the synthesis of branched azasugars

Svenja Domeyer; Mark Bjerregaard; Henrik Johansson; Daniel Sejer Pedersen

doi:10.3762/bjoc.13.63

Exploring endoperoxides as a new entry for the synthesis of branched azasugars

Svenja Domeyer, Mark Bjerregaard, Henrik Johansson, Daniel Sejer Pedersen

3 Citationer (Scopus)

59 Downloads (Pure)

Abstract

A new class of nitrogen-containing endoperoxides were synthesised by a photochemical [4 + 2]-cycloaddition between a diene and singlet oxygen. The endoperoxides were dihydroxylated and protected to provide a series of endoperoxide building blocks for organic synthesis, with potential use as precursors for the synthesis of branched azasugars. Preliminary exploration of the chemistry of these building blocks provided access to a variety of derivatives including tetrahydrofurans, epoxides and protected amino-tetraols.

Originalsprog	Engelsk
Tidsskrift	Beilstein Journal of Organic Chemistry
Vol/bind	13
Sider (fra-til)	644-647
Antal sider	4
ISSN	2195-951X
DOI	https://doi.org/10.3762/bjoc.13.63
Status	Udgivet - 3 apr. 2017

Adgang til dokumentet

10.3762/bjoc.13.63Licens: CC BY

1860-5397-13-63Licens: CC BY

Citationsformater

@article{1808dfed33154c068b356cf3367e6365,

title = "Exploring endoperoxides as a new entry for the synthesis of branched azasugars",

abstract = "A new class of nitrogen-containing endoperoxides were synthesised by a photochemical [4 + 2]-cycloaddition between a diene and singlet oxygen. The endoperoxides were dihydroxylated and protected to provide a series of endoperoxide building blocks for organic synthesis, with potential use as precursors for the synthesis of branched azasugars. Preliminary exploration of the chemistry of these building blocks provided access to a variety of derivatives including tetrahydrofurans, epoxides and protected amino-tetraols.",

keywords = "Journal Article",

author = "Svenja Domeyer and Mark Bjerregaard and Henrik Johansson and {Sejer Pedersen}, Daniel",

year = "2017",

month = apr,

day = "3",

doi = "10.3762/bjoc.13.63",

language = "English",

volume = "13",

pages = "644--647",

journal = "Beilstein Journal of Organic Chemistry",

issn = "2195-951X",

publisher = "Beilstein - Institut zur Foerderung der Chemischen Wissenschaften",

}

TY - JOUR

T1 - Exploring endoperoxides as a new entry for the synthesis of branched azasugars

AU - Domeyer, Svenja

AU - Bjerregaard, Mark

AU - Johansson, Henrik

AU - Sejer Pedersen, Daniel

PY - 2017/4/3

Y1 - 2017/4/3

N2 - A new class of nitrogen-containing endoperoxides were synthesised by a photochemical [4 + 2]-cycloaddition between a diene and singlet oxygen. The endoperoxides were dihydroxylated and protected to provide a series of endoperoxide building blocks for organic synthesis, with potential use as precursors for the synthesis of branched azasugars. Preliminary exploration of the chemistry of these building blocks provided access to a variety of derivatives including tetrahydrofurans, epoxides and protected amino-tetraols.

AB - A new class of nitrogen-containing endoperoxides were synthesised by a photochemical [4 + 2]-cycloaddition between a diene and singlet oxygen. The endoperoxides were dihydroxylated and protected to provide a series of endoperoxide building blocks for organic synthesis, with potential use as precursors for the synthesis of branched azasugars. Preliminary exploration of the chemistry of these building blocks provided access to a variety of derivatives including tetrahydrofurans, epoxides and protected amino-tetraols.

KW - Journal Article

U2 - 10.3762/bjoc.13.63

DO - 10.3762/bjoc.13.63

M3 - Journal article

C2 - 28487758

SN - 2195-951X

VL - 13

SP - 644

EP - 647

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

ER -

Exploring endoperoxides as a new entry for the synthesis of branched azasugars

Abstract

Adgang til dokumentet

Fingeraftryk

Citationsformater