Electrocatalytic CO 2 reduction using modified electrodes

Shlomi Elias; Jonathan Quinson; George J.P. Britovsek; Anthony R.J. Kucernak

Electrocatalytic CO ₂ reduction using modified electrodes

Shlomi Elias^*, Jonathan Quinson, George J.P. Britovsek, Anthony R.J. Kucernak

^*Corresponding author af dette arbejde

Kemisk Institut

Abstract

CO ₂ is the planet's most important atmospheric contribution to the greenhouse effect. The electrochemical reduction of CO ₂ into fuels attracts sustained attention. A large variety of transition metal complexes has been studied as electrocatalysts, however only few appear to be effective in pure aqueous electrolyte. The accompanying reduction of protons limits the efficiency of the electrocatalysis. One solution to this problem is to use complexes in a polymer-confined system deposited on metallic cathode surfaces.1 Here we present an approach to the modification of surfaces of solid electrodes by applying electrically conducting polymers containing immobilized complexes bearing multidentate nitrogen based ligands.

Originalsprog	Engelsk
Tidsskrift	ACS National Meeting Book of Abstracts
ISSN	0065-7727
Status	Udgivet - 1 dec. 2011
Begivenhed	242nd ACS National Meeting and Exposition - Denver, CO, USA Varighed: 28 aug. 2011 → 1 sep. 2011

Konference

Konference	242nd ACS National Meeting and Exposition
Land/Område	USA
By	Denver, CO
Periode	28/08/2011 → 01/09/2011

Andre filer og links

Link to publication in Scopus

Citationsformater

@inproceedings{da7ba398686847ff81a60c09c54900ff,

title = "Electrocatalytic CO 2 reduction using modified electrodes",

abstract = "CO 2 is the planet's most important atmospheric contribution to the greenhouse effect. The electrochemical reduction of CO 2 into fuels attracts sustained attention. A large variety of transition metal complexes has been studied as electrocatalysts, however only few appear to be effective in pure aqueous electrolyte. The accompanying reduction of protons limits the efficiency of the electrocatalysis. One solution to this problem is to use complexes in a polymer-confined system deposited on metallic cathode surfaces.1 Here we present an approach to the modification of surfaces of solid electrodes by applying electrically conducting polymers containing immobilized complexes bearing multidentate nitrogen based ligands.",

author = "Shlomi Elias and Jonathan Quinson and Britovsek, {George J.P.} and Kucernak, {Anthony R.J.}",

year = "2011",

month = dec,

day = "1",

language = "English",

journal = "American Chemical Society. Abstracts of Papers (at the National Meeting)",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "242nd ACS National Meeting and Exposition ; Conference date: 28-08-2011 Through 01-09-2011",

}

TY - GEN

T1 - Electrocatalytic CO 2 reduction using modified electrodes

AU - Elias, Shlomi

AU - Quinson, Jonathan

AU - Britovsek, George J.P.

AU - Kucernak, Anthony R.J.

PY - 2011/12/1

Y1 - 2011/12/1

N2 - CO 2 is the planet's most important atmospheric contribution to the greenhouse effect. The electrochemical reduction of CO 2 into fuels attracts sustained attention. A large variety of transition metal complexes has been studied as electrocatalysts, however only few appear to be effective in pure aqueous electrolyte. The accompanying reduction of protons limits the efficiency of the electrocatalysis. One solution to this problem is to use complexes in a polymer-confined system deposited on metallic cathode surfaces.1 Here we present an approach to the modification of surfaces of solid electrodes by applying electrically conducting polymers containing immobilized complexes bearing multidentate nitrogen based ligands.

AB - CO 2 is the planet's most important atmospheric contribution to the greenhouse effect. The electrochemical reduction of CO 2 into fuels attracts sustained attention. A large variety of transition metal complexes has been studied as electrocatalysts, however only few appear to be effective in pure aqueous electrolyte. The accompanying reduction of protons limits the efficiency of the electrocatalysis. One solution to this problem is to use complexes in a polymer-confined system deposited on metallic cathode surfaces.1 Here we present an approach to the modification of surfaces of solid electrodes by applying electrically conducting polymers containing immobilized complexes bearing multidentate nitrogen based ligands.

UR - http://www.scopus.com/inward/record.url?scp=84861087463&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:84861087463

SN - 0065-7727

JO - American Chemical Society. Abstracts of Papers (at the National Meeting)

JF - American Chemical Society. Abstracts of Papers (at the National Meeting)

T2 - 242nd ACS National Meeting and Exposition

Y2 - 28 August 2011 through 1 September 2011

ER -