Confluence of disparate carbido chemistries: [WRuAu₂(μ-C)₂Cl₂(CO)₂(PCy₃)₂(Tp*)]

TY - JOUR

T1 - Confluence of disparate carbido chemistries

T2 - [WRuAu2(μ-C)2Cl2(CO)2(PCy3)2(Tp*)]

AU - Reinholdt, Anders

AU - Bendix, Jesper

AU - Hill, Anthony F.

AU - Manzano, Richard A.

PY - 2018

Y1 - 2018

N2 - The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(CSnnBu3)(CO)2(Tp*)] (obtained from [W(CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.

AB - The reaction of [Ru(CAuCl)Cl2(PCy3)2] with [W(CSnnBu3)(CO)2(Tp*)] (obtained from [W(CBr)(CO)2(Tp*)], nBuLi and ClSnnBu3) affords the heterotetrametallic bis(carbido) complex [WRuAu2(μ-C)2Cl3(CO)2(PCy3)2(Tp*)] in which the two distinct μ-carbido ligands adopt linear and T-shaped geometry at carbon.

U2 - 10.1039/C8DT03851A

DO - 10.1039/C8DT03851A

M3 - Journal article

SN - 1477-9226

VL - 47

SP - 14893

EP - 14896

JO - Dalton Transactions

JF - Dalton Transactions

IS - 42

ER -