cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate

TY - JOUR

T1 - cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate

AU - Birk, Torben

AU - Bendix, Jesper

AU - Weihe, Högni

PY - 2008

Y1 - 2008

N2 - The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.

AB - The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.

U2 - 10.1107/S1600536808001153

DO - 10.1107/S1600536808001153

M3 - Journal article

C2 - 21201326

SN - 1600-5368

VL - E64

SP - m369-m370

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - Pt 2

ER -