Chemical signals turn on guest binding through structural reconfiguration of triangular helicates

Anne Sørensen, Ana M. Castilla, Tanya K. Ronson, Michael Pittelkow, Jonathan R. Nitschke

38 Citationer (Scopus)

Abstract

Be my guest: The function of a system based on self-assembled Zn(II) complexes can be controlled by external chemical stimuli. The complexes are based on a C3 -symmetric ligand that forms a unique triangular triple helicate structure 1. Upon subcomponent substitution, 1 is able to transform into a triangular double helicate 2 which, unlike 1, can encapsulate guests.
OriginalsprogEngelsk
TidsskriftAngewandte Chemie International Edition
Vol/bind52
Udgave nummer43
Sider (fra-til)11273-11277
Antal sider5
ISSN1433-7851
DOI
StatusUdgivet - 18 okt. 2013

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