@article{8967e8e0b28011debc73000ea68e967b,
title = "Attempting to understand (and control) the relationship between structure and magnetism in an extended family of Mn(6) single-molecule magnets",
abstract = "The synthesis and characterisation of a large family of hexametallic [Mn(III)(6)] Single-Molecule Magnets of general formula [Mn(III)(6)O(2)(R-sao)(6)(X)(2)(sol)(4-6)] (where R = H, Me, Et; X = (-)O(2)CR' (R' = H, Me, Ph etc) or Hal(-); sol = EtOH, MeOH and/or H(2)O) are presented. We show how deliberate structural distortions of the [Mn(3)O] trinuclear moieties within the [Mn(6)] complexes are used to tune their magnetic properties. These findings highlight a qualitative magneto-structural correlation whereby the type (anti- or ferromagnetic) of each Mn(2) pairwise magnetic exchange is dominated by the magnitude of each individual Mn-N-O-Mn torsion angle. The observation of magneto-structural correlations on such large polymetallic complexes is rare and represents one of the largest studies of this kind.",
author = "Ross Inglis and Jones, {Leigh F} and Milios, {Constantinos J} and Saiti Datta and Anna Collins and Simon Parsons and Wolfgang Wernsdorfer and Stephen Hill and Perlepes, {Spyros P} and Stergios Piligkos and Brechin, {Euan K}",
year = "2009",
doi = "10.1039/b822235e",
language = "English",
pages = "3403--12",
journal = "Dalton Transactions (Print Edition)",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "18",
}