Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch.

Christian Richard Parker; Christian Gregers Tortzen; Søren Lindbæk Broman; Magnus Schau-Magnussen; Kristine Kilså; Mogens Brøndsted Nielsen

Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch.

Christian Richard Parker, Christian Gregers Tortzen, Søren Lindbæk Broman, Magnus Schau-Magnussen, Kristine Kilså, Mogens Brøndsted Nielsen

Department of Chemistry

27 Citations (Scopus)

Abstract

Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.

Original language	English
Journal	Chemical communications (Cambridge, England)
Volume	47
Pages (from-to)	6102-6104
Publication status	Published - 7 Jun 2011

Cite this

@article{ace2c82435e84991bcbba86d2254d183,

title = "Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch.",

abstract = "Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.",

author = "Parker, {Christian Richard} and Tortzen, {Christian Gregers} and Broman, {S{\o}ren Lindb{\ae}k} and Magnus Schau-Magnussen and Kristine Kils{\aa} and Nielsen, {Mogens Br{\o}ndsted}",

year = "2011",

month = jun,

day = "7",

language = "English",

volume = "47",

pages = "6102--6104",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch.

AU - Parker, Christian Richard

AU - Tortzen, Christian Gregers

AU - Broman, Søren Lindbæk

AU - Schau-Magnussen, Magnus

AU - Kilså, Kristine

AU - Nielsen, Mogens Brøndsted

PY - 2011/6/7

Y1 - 2011/6/7

N2 - Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.

AB - Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.

M3 - Journal article

SN - 1359-7345

VL - 47

SP - 6102

EP - 6104

JO - Chemical Communications

JF - Chemical Communications

ER -

Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch.

Abstract

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