Isomerization of metastable amine radical cations by dissociation-recombination

Anders Holmen Pedersen; Christian Benedikt Nielsen; Gustav Bojesen; Steen Hammerum

doi:10.1255/ejms.1342

Isomerization of metastable amine radical cations by dissociation-recombination

Anders Holmen Pedersen, Christian Benedikt Nielsen, Gustav Bojesen, Steen Hammerum

1 Citation (Scopus)

Abstract

The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.

Original language	English
Journal	European Journal of Mass Spectrometry
Volume	21
Issue number	3
Pages (from-to)	635-639
Number of pages	5
ISSN	1469-0667
DOIs	https://doi.org/10.1255/ejms.1342
Publication status	Published - 7 Jun 2015

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title = "Isomerization of metastable amine radical cations by dissociation-recombination",

abstract = "The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.",

author = "Pedersen, {Anders Holmen} and Nielsen, {Christian Benedikt} and Gustav Bojesen and Steen Hammerum",

year = "2015",

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language = "English",

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T1 - Isomerization of metastable amine radical cations by dissociation-recombination

AU - Pedersen, Anders Holmen

AU - Nielsen, Christian Benedikt

AU - Bojesen, Gustav

AU - Hammerum, Steen

PY - 2015/6/7

Y1 - 2015/6/7

N2 - The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.

AB - The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.

U2 - 10.1255/ejms.1342

DO - 10.1255/ejms.1342

M3 - Journal article

C2 - 26307742

SN - 1469-0667

VL - 21

SP - 635

EP - 639

JO - European Journal of Mass Spectrometry

JF - European Journal of Mass Spectrometry

IS - 3

ER -

Isomerization of metastable amine radical cations by dissociation-recombination

Abstract

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