A tetrathiafulvalene-functionalized radiaannulene with multiple redox states

Kasper Lincke Rue; Anders Floor Frellsen; Christian Richard Parker; Andrew Bond; Ole Hammerich; Mogens Brøndsted Nielsen

doi:10.1002/anie.201202324

A tetrathiafulvalene-functionalized radiaannulene with multiple redox states

Kasper Lincke Rue, Anders Floor Frellsen, Christian Richard Parker, Andrew Bond, Ole Hammerich, Mogens Brøndsted Nielsen

Department of Chemistry

32 Citations (Scopus)

Abstract

Multiple states: Fusing a central expanded radiaannulene (RA) core with two tetrathiafulvalene (TTF) units furnishes a molecule that can exist in several redox states with characteristic UV/Vis/IR absorptions. The radical cation was found to be of mixed valence (MV) character as reflected by a low-energy intervalence transition.

Original language	English
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	25
Pages (from-to)	6099–6102
Number of pages	4
ISSN	1433-7851
DOIs	https://doi.org/10.1002/anie.201202324
Publication status	Published - 18 Jun 2012

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10.1002/anie.201202324

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abstract = "Multiple states: Fusing a central expanded radiaannulene (RA) core with two tetrathiafulvalene (TTF) units furnishes a molecule that can exist in several redox states with characteristic UV/Vis/IR absorptions. The radical cation was found to be of mixed valence (MV) character as reflected by a low-energy intervalence transition.",

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AU - Bond, Andrew

AU - Hammerich, Ole

AU - Nielsen, Mogens Brøndsted

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N2 - Multiple states: Fusing a central expanded radiaannulene (RA) core with two tetrathiafulvalene (TTF) units furnishes a molecule that can exist in several redox states with characteristic UV/Vis/IR absorptions. The radical cation was found to be of mixed valence (MV) character as reflected by a low-energy intervalence transition.

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A tetrathiafulvalene-functionalized radiaannulene with multiple redox states

Abstract

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