A convenient alternative route for the synthesis of Bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene

Marta Vico Solano; Mogens Brøndsted Nielsen; Jan Oskar Jeppesen

doi:10.1002/jhet.2046

A convenient alternative route for the synthesis of Bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene

Marta Vico Solano, Mogens Brøndsted Nielsen, Jan Oskar Jeppesen

Department of Chemistry

1 Citation (Scopus)

Abstract

An alternative and efficient protocol for the synthesis of methylated pyrrolo-tetrathiafulvalenes have been developed. The key intermediate in this new synthetic protocol is 4,6-dimethyl-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one, which can be obtained in high yield in a three-step synthetic procedure from 5-dimethyl-3,4-dithiocyanopyrrole.

Original language	English
Journal	Journal of Heterocyclic Chemistry
Volume	53
Issue number	3
Pages (from-to)	915-918
Number of pages	4
ISSN	1943-5193
DOIs	https://doi.org/10.1002/jhet.2046
Publication status	Published - 1 May 2016

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10.1002/jhet.2046

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title = "A convenient alternative route for the synthesis of Bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene",

abstract = "An alternative and efficient protocol for the synthesis of methylated pyrrolo-tetrathiafulvalenes have been developed. The key intermediate in this new synthetic protocol is 4,6-dimethyl-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one, which can be obtained in high yield in a three-step synthetic procedure from 5-dimethyl-3,4-dithiocyanopyrrole.",

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AU - Vico Solano, Marta

AU - Nielsen, Mogens Brøndsted

AU - Jeppesen, Jan Oskar

PY - 2016/5/1

Y1 - 2016/5/1

N2 - An alternative and efficient protocol for the synthesis of methylated pyrrolo-tetrathiafulvalenes have been developed. The key intermediate in this new synthetic protocol is 4,6-dimethyl-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one, which can be obtained in high yield in a three-step synthetic procedure from 5-dimethyl-3,4-dithiocyanopyrrole.

AB - An alternative and efficient protocol for the synthesis of methylated pyrrolo-tetrathiafulvalenes have been developed. The key intermediate in this new synthetic protocol is 4,6-dimethyl-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one, which can be obtained in high yield in a three-step synthetic procedure from 5-dimethyl-3,4-dithiocyanopyrrole.

U2 - 10.1002/jhet.2046

DO - 10.1002/jhet.2046

M3 - Journal article

SN - 0022-152X

VL - 53

SP - 915

EP - 918

JO - Journal of Heterocyclic Chemistry

JF - Journal of Heterocyclic Chemistry

IS - 3

ER -

A convenient alternative route for the synthesis of Bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene

Abstract

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