Abstract
Separation of redox-active or chromophoric units by cross-conjugated bridges has a significant impact on the communication between these groups. Thus, a cross-conjugated bridge decreases the electronic communication between two redox centers or a donor-acceptor system in comparison to a linearly conjugated one as revealed by electrochemical, optical, and molecular conductance studies. This chapter illustrates the influence of cross-conjugation in a variety of expanded systems, ranging from extended tetrathiafulvalenes, bimetallic species, cyclic scaffolds like radiaannulenes, dendralenes, quinones, to simple o-, m-, and p-substituted benzenes.
| Originalsprog | Engelsk |
|---|---|
| Titel | Cross-conjugation : modern dendralene, radialene and fulvene chemistry |
| Redaktører | Henning Hopf, Michael S. Sherburn |
| Antal sider | 27 |
| Forlag | Wiley-VCH |
| Publikationsdato | 8 apr. 2016 |
| Sider | 337-363 |
| Kapitel | 9 |
| ISBN (Trykt) | 978-3-527-33437-7 |
| ISBN (Elektronisk) | 978-3-527-67121-2, 978-3-527-67118-2 |
| DOI | |
| Status | Udgivet - 8 apr. 2016 |